Abstract
Based on the mineralogical characterization for the polymetallic sulfide ore, the way to improve silver recovery was studied. The results showed that silver was the most valuable metal whose grade was 448.82 g/t Ag, while 0.118% Cu, 1.65% Pb and 1.06% Zn may be comprehensively utilizated. The main silver-bearing minerals were argent and aregentite which accounted for 87.18% of total silver. Argentite and other metal minerals were distributed in the gangue minerals in complex forms. Argentite grains of 33.76% minus 50 μm indicated that a fine grinding scheme was necessary to enhance the degree of dissociation, and meanwhile selective grinding must be considered to prevent a complete grinding of coarse grains. The optimum regrinding fineness in the Cu flotation was determined as 73% minus 37 μm, while grains of 68.5% minus 74 μm in one-stage grinding remained unchanged as much as possible. Consequently, silver recovery increased to 2.68%, as well as the content of Pb simultaneously decreased from 7.26% to 2.68% in the Cu concentrate. From the lead pyrometallurgical point of view, recovering larger amounts of silver and lead at the expense of decreasing the grade of lead to a suitable level is not only economically viable for the plant, but also convenient for subsequent processing. Silver and lead recovery increased to 13.18% and 12.58%, respectively, while the Pb grade decreased from 53.1% to 46.12% for the Pb concentrate.
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References
Bogusz E, Brienne S R, Butler I, et al. Metal Ions and Dextrin Adsorption on Pyrite[J]. Minerals Engineering, 1997, 10(4): 441–445
Bulatovic S M. Flotation Behaviour of Gold during Processing of Porphyry Copper-gold Ores and Refractory Gold-bearing Sulphides[J]. Minerals Engineering, 1997, 10(9): 895–908
Bulatovic S, Wysouzil D M, Bermejo F C. Development and Introduction of a New Copper/lead Separation Method in the Raura Plant (Peru) [J]. Minerals Engineering, 2001, 14(14): 1483–1491
Drzymala J, Kapusniak J, Tomasik P. Removal of Lead Minerals from Copper Industrial Flotation Concentrates by Xanthate Flotation in the Presence of Dextrin[J]. International Journal of Mineral Processing, 2003, 70(70): 147–155
Philip K Gbor, Valentina Mokri, Charles Q Jia. Characterization of Smelter Slags[J]. Journal of Environmental Science & Health Part A, 2000, 35(2): 147–167
Baoliang Ge, Siqing Liu, Qi Nie, et al. Applying One-Stage Grinding and Flotation to Improving Copper Recovery of a Fine-Grained Cu-Mo Sulphide Ore[J]. Separation Science and Technology, 2012, 48(12): 1900–1905
Grano S R, Cnossen H, Skinner W, et al. Surface Modifications in the Chalcopyrite-sulphite Ion System, II. Dithiophosphate Collector Adsorption Study[J]. International Journal of Mineral Processing, 1997, 50(1–2): 27–45
Liu Q, Zhang Y. Effect of Calcium Ions and Citric Acid on the Flotation Separation of Chalcopyrite from Galena Using Dextrin[J]. Minerals Engineering, 2000, 13(13): 1405–1416
Liu Q, Zhang Y, Laskowski J S. The Adsorption of Polysaccharides onto Mineral Surfaces: an Acid/base Interaction[J]. International Journal of Mineral Processing, 2000, 60(60): 229–245
PAN Zhihua, ZHANG Jun, Liu W. Solidification/Stabilization of Zinclead Tailings by Alkali Activated Slag Cement[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2015, 30(1): 105–108
Raju G B, Holmgren A, Forsling W. Complexation Mechanism of Dextrin with Metal Hydroxides[J]. Journal of Colloid & Interface Science, 1998, 200(1): 1–6
Rashchi F, Finch J A. Polyphosphates: A Review Their Chemistry and Application with Particular Reference to Mineral Processing[J]. Minerals Engineering, 2000, 13(10–11): 1019–1035
Schouwstra R, Vaux D D, Hey P, et al. Understanding Gamsberg-A geometallurgical Study of a Large Stratiform Zinc Deposit[J]. Minerals Engineering, 2010, 23(11–13): 960–967
Schouwstra R P, Smit A J. Developments in Mineralogical Techniques-What about Mineralogists[J]? Minerals Engineering, 2011, 24(12): 1224–1228
Shen H, Forssberg E, Nordström U. Physicochemical and Mineralogical Properties of Stainless Steel Slags Oriented to Metal Recovery[J]. Resources Conservation & Recycling, 2004, 40(3): 245–271
Spear T M, Svee W, Vincent J H, et al. Chemical Speciation of Lead Dust Associated with Primary Lead Smelting[J]. Environmental Health Perspectives, 1998, 106(9): 565–571
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Funded by the National Natural Science Foundation of China (No. 51374247)
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Chen, D., Xiao, J. Mineralogical characterization of a polymetallic sulfide ore to improve silver recovery. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 32, 501–507 (2017). https://doi.org/10.1007/s11595-017-1625-7
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DOI: https://doi.org/10.1007/s11595-017-1625-7