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Promotion effect of nickel for Cu–Ni/γ-Al2O3 catalysts in the transfer dehydrogenation of primary aliphatic alcohols

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Abstract

Cu–Ni/γ-Al2O3 bimetallic catalysts were developed for anaerobic dehydrogenation of non-activated primary aliphatic alcohols to aldehydes. Systematic investigation about the promotion effect of nickel on the catalytic performance was carried out. Hydrogenation of C=C bond rather than C=O bond, was significantly improved over Cu–Ni/γ-Al2O3 catalyst by introducing nickel, which interprets the good conversion of primary aliphatic alcohols. This work would contribute to design new catalysts for dehydrogenation of primary aliphatic alcohols.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Grant: U1304209), the Key Scientific Research Projects for University in Henan Province (16A530009) and the Foundation for University Young Key Teacher by Henan Province (Grant: 2014GGJS-005).

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Authors and Affiliations

  1. College of Chemistry and Molecular Engineering, Zhengzhou University, 100 Kexue Road, Zhengzhou, 450001, People’s Republic of China

    Xiaomei Yang, Xiaomin Fu, Yunlai Su & Lipeng Zhou

  2. Research Center of Heterogeneous Catalysis and Engineering Sciences, School of Chemical Engineering and Energy, Zhengzhou University, 100 Kexue Road, Zhengzhou, 450001, People’s Republic of China

    Ningning Bu, Li Han, Jianfeng Wang, Chengying Song & Tianliang Lu

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  1. Xiaomei Yang
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  2. Xiaomin Fu
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Correspondence to Tianliang Lu.

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Yang, X., Fu, X., Bu, N. et al. Promotion effect of nickel for Cu–Ni/γ-Al2O3 catalysts in the transfer dehydrogenation of primary aliphatic alcohols. J IRAN CHEM SOC 14, 111–119 (2017). https://doi.org/10.1007/s13738-016-0963-2

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  • DOI: https://doi.org/10.1007/s13738-016-0963-2

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