A novel and facile synthetic strategy for the construction of 1-benzazepines has been developed via copper-catalyzed oxidative C(sp3)–H/C(sp2)–H cross-coupling directly from two inert C–H bonds. This transformation represents an atom- and step-economical way to synthesize biologically important seven-membered benzo-heterocycles compared with the known methods.
R. Wang, R. Jin, Z. Qin, K. Bian and X. Wang, Chem. Commun., 2017, 53, 12229 DOI: 10.1039/C7CC07027F
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