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A Disc-Like Heptanuclear Nickel Cluster Based on Schiff Base: Synthesis, Structure, Magnetic Properties and Hirshfeld Surface Analysis

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Abstract

A new disc-like heptanuclear cluster [Ni7(immep)6(MeO)6]·(NO3)2 (1, Himmep is 2-imminomethyl-6-ethxoy-phenol) was synthesized through microwave assisted reaction of Ni(NO3)2·6H2O with 2-hydroxy-3-ethoxy-benzaldehyde and ammonium water in mixed solvent (acetonitrile:methanol = 1:1). 1 was characterized by IR spectroscopy, elemental analysis and X-ray single-crystal diffraction. Magnetic property of 1 was discussed. The core of 1 displays dominant ferromagnetic interactions from the nature of the binding modes through μ 3-OCH3. According to the 3D Hirshfeld surface and 2D fingerprint plots, the main interactions in 1 are the H···H, O···H, and C···H contacts.

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Acknowledgments

This work is financially supported by the National Nature Science Foundation of China (No. 51569008), the Nature Science Foundation of Guangxi Province of China (No. 2015GXNSFAA139240) and Guangxi Scientific Experiment Center of Mining, Metallurgy and Environment (No. KH2012ZD004).

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Authors and Affiliations

  1. Guangxi Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area, Guilin University of Technology, Guilin, 541004, China

    Yu Xiao, Yan Qin, Ming Yi & Yun Zhu

Authors
  1. Yu Xiao
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  2. Yan Qin
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  3. Ming Yi
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  4. Yun Zhu
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Correspondence to Yu Xiao.

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Xiao, Y., Qin, Y., Yi, M. et al. A Disc-Like Heptanuclear Nickel Cluster Based on Schiff Base: Synthesis, Structure, Magnetic Properties and Hirshfeld Surface Analysis. J Clust Sci 27, 2013–2023 (2016). https://doi.org/10.1007/s10876-016-1059-y

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