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A Solvent-Stable Zinc(II)–Gadolinium(III) Metal–Organic Framework Assembled with Furan-2,5-Dicarboxylic Acid: Synthesis, Crystal Structure and Magnetic Property

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Abstract

A novel three-dimensional 3d–4f metal–organic framework (MOF), {[(CH3)2NH2]2[Zn2Gd2(FDA)6(DMF)2]·2DMF}n (Zn–Gd) (H2FDA = furan-2,5-dicarboxylic acid) assembled with furan-2,5-dicarboxylic acid has been isolated and characterized by infrared spectra, elemental analysis, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. Structure analysis indicates this MOF is an interesting three-dimensional 8-connected bcu body centered cubic topological net. Moreover, Zn–Gd MOF shows a tolerance towards moisture and the corresponding solvents, demonstrating the excellent chemical stability. The magnetic property of Zn–Gd MOF suggests a weak antiferromagnetic coupling interaction between adjacent Gd(III) ions in Zn–Gd MOF.

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Acknowledgements

Financial supports from the National Natural Science Foundation of China (Nos. 21561014 and 21562023), the Key Research Project of Jiangxi Province (No. 20171BBF60074) and the Key Research Project of Jiangxi Academy of Sciences (No. 2018-YZD2-11) are greatly acknowledged.

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Authors and Affiliations

  1. Institute of Applied Chemistry, Jiangxi Academy of Sciences, Nanchang, 330096, People’s Republic of China

    Ji-Yong Zou, Ling Li, Sheng-Yong You, Yue-Wei Liu, Hong-Min Cui & Kai-Hong Chen

  2. Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of the Ministry of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, Hunan, People’s Republic of China

    Shao-Wei Zhang

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  1. Ji-Yong Zou
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  2. Ling Li
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Correspondence to Ji-Yong Zou.

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Zou, JY., Li, L., You, SY. et al. A Solvent-Stable Zinc(II)–Gadolinium(III) Metal–Organic Framework Assembled with Furan-2,5-Dicarboxylic Acid: Synthesis, Crystal Structure and Magnetic Property. J Inorg Organomet Polym 29, 359–364 (2019). https://doi.org/10.1007/s10904-018-1006-5

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  • DOI: https://doi.org/10.1007/s10904-018-1006-5

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