Issue 16, 2012
From the journal:

CrystEngComm

A mixed-valence lanthanide metal–organic framework, templated by 2,2′-bipyridine formed in situ reaction: synthesis, structure, and luminescent properties†‡

Bowei Cai,ab   Yanwei Ren,a   Huanfeng Jiang,*a   De Zheng,b   Dabin Shi,a   Yuying Qianb  and  Jun Chenb  

* Corresponding authors

a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, P. R. China
E-mail: jianghf@scut.edu.cn
Tel: + 86 20 87112906

b Guangdong Winner Functional Materials Co., Ltd, Foshan, P. R. China

Abstract

A novel lanthanide metal–organic framework, {(bpy)0.5[Dy3(ip)4(phen)4(H2O)]·2H2O}n has been synthesized via a hydrothermal method. Single-crystal X-ray analysis reveals that the center ions are mixed-valence Dy (II, III) and that trans-2,2′-bipyridine was formed in situ from 1,10-phenanthroline under hydrothermal conditions in the presence of Dy(III) ions.

Graphical abstract: A mixed-valence lanthanide metal–organic framework, templated by 2,2′-bipyridine formed in situ reaction: synthesis, structure, and luminescent properties

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Article information

DOI
https://doi.org/10.1039/C2CE25160D
Article type
Paper
Submitted
05 Feb 2012
Accepted
31 May 2012
First published
06 Jun 2012

CrystEngComm, 2012,14, 5285-5288

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A mixed-valence lanthanide metal–organic framework, templated by 2,2′-bipyridine formed in situ reaction: synthesis, structure, and luminescent properties

B. Cai, Y. Ren, H. Jiang, D. Zheng, D. Shi, Y. Qian and J. Chen, CrystEngComm, 2012, 14, 5285 DOI: 10.1039/C2CE25160D

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